Technically Thor wasn’t even part of the avengers initiative. He just showed up to the party.
At first, we see
then we fain at his eyebrow lift and subtle smile
then we’re hooked by his charm
But all of a sudden it surprises us
When he does this
and especially this
and we panic a little
but you can try as hard as you want
But you’ll never getting away
so Just accept it
Besides, who wouldn’t want a piece of this?